Entropy and Second Law of Thermodynamics

IMPORTANT

Entropy and Second Law of Thermodynamics: Overview

This topic covers concepts, such as, Entropy, Factors Affecting Entropy, Entropy Change for Phase Transition & Entropy Change for Ideal Gases etc.

Important Questions on Entropy and Second Law of Thermodynamics

MEDIUM
IMPORTANT

For vaporization of water at 1 atmospheric pressure, the values of   ΔHandΔSare40.63kJmo l 1 and108.8J K 1 mo l 1 , respectively. The temperature when Gibbs energy change   (ΔG) for this transformation will be zero, is:

                               

MEDIUM
IMPORTANT

The values of  ΔH  and  ΔS for the reaction, C(graphite)+CO2(g)2CO(g)are170kJand170JK1, respectively. This reaction will be spontaneous at

                               

EASY
IMPORTANT

Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is:

                               

EASY
IMPORTANT

2 mol of an ideal gas at  27°C temperature is expanded reversibly from 2 L to 20 L. Find the entropy change. R=2 cal/mol K    

MEDIUM
IMPORTANT

The adsorption of a gas at the boiling point of the gas follows the isotherm shown in the figure. Identify the correct thermodynamic properties at point C.

Question Image

EASY
IMPORTANT

A heat engine absorbs heat Q1 at temperature T1 and heat Q2 at temperature T2. Work done by the engine is Q1+Q2 J. This data

MEDIUM
IMPORTANT

For which of the following processes, S is negative?

HARD
IMPORTANT

The molar heat capacity (Cp) of CD2O is 10 cal at 1000K. The change in entropy associated with cooling of 32g of CD2O vapour from1000K-100K at constant pressure will be : (D = deuterium, Atomic mass = 2

MEDIUM
IMPORTANT

The enthalpy of vaporization of water at 100°C is 40.63 kJmol-1. Its entropy of vaporization would be

MEDIUM
IMPORTANT

The SI unit of S is 

MEDIUM
IMPORTANT

What does entropy measure?

HARD
IMPORTANT

A container is divided into two compartments by a removable partition as shown below:

Question Image

In the first compartment, n1 moles of ideal gas He is present in a volume V1. In the second compartment, n2 moles of ideal gas Ne is present in a volume V2. The temperature and pressure in both the compartments are T and P, respectively. Assuming R is the gas constant, the total change in entropy upon removing the partition when the gases mix irreversibly is:

MEDIUM
IMPORTANT

The change in entropy at equilibrium is 

MEDIUM
IMPORTANT

The enthalpy of vaporization of water at 100°C is 40.63 kJmol-1. Its entropy of vaporization would be

EASY
IMPORTANT

ΔS will be highest for

EASY
IMPORTANT

Among the following processes, for which process the change in entropy ΔS is negative?

HARD
IMPORTANT

2 mole of an ideal gas at 27°C expands reversibly from 2 litre to 20 litre. The entropy change is: R=2 cal mol-1 K-1

HARD
IMPORTANT

A sample of an ideal gas is expanded to twice its original volume of 1 m3 in a reversible process for which  α = 5 atm  m - 6   and  C Vm = 20 J K -1 m -1 at constant volume.

The entropy change during the process may be (polytropic process given by function P = αv2)

HARD
IMPORTANT

The standard entropy change accompanying the cell reaction will be